Radical Amido‐ and Azido‐Fluorination of <i>α</i> ‐Fluorostyrene Derivatives: An Innovative Approach Towards <i>β</i> ‐Aryl‐ <i>β</i> , <i>β</i> ‐difluoroamino Motifs

An innovative one-step synthesis towards β-aryl-β,β-difluorocarbamates and β-aryl-β,β-difluoroazides is presented. The described approach relies on the use of α-fluorostyrene substrates in a radical addition/fluorination reaction with N-centered radicals presence Selectfluor®. best results were obtained for azidofluorination reaction. resultant further transformed into Nitrogen-based heterocycles (e. g. pyrrole, triazole, tetrazole) more elaborated azide derivatives.